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71.
Xingbin Ma Xukun Zhang Hongling Lin A. M. Abd El‐Aty Tsdan Rabah Xiaoxi Liu Zhichao Yu Yanhong Yong Xianghong Ju Yongxin She 《Journal of separation science》2020,43(12):2301-2310
The naturally occurring quercetin flavonoid, dihydroquercetin, is widely distributed in plant tissues and has a variety of biological activities. Herein, a magnetic molecularly imprinted solid‐phase extraction was tailor made for selective determination of dihydroquercetin in Larix griffithiana using high‐performance liquid chromatography. Amino‐functionalized core‐shell magnetic nanoparticles were prepared and characterized using scanning electron microscopy, transmission electron microscopy, vibrating sample magnetometry, and infrared spectroscopy. The polymer had an average diameter of 250 ± 2.56 nm and exhibited good stability and adsorption for template molecule, which is enriched by hydrogen bonding interaction. Multiple factors for extraction, including loading, washing, elution solvents, and extraction time, were optimized. The limit of detection was 1.23 μg/g. The precision determined at various concentration of dihydroquercetin was less than 4% and the mean recovery was between 74.64 and 101.80%. It has therefore been shown that this protocol can be used as an alternative extraction to quantify dihydroquercetin in L. griffithiana and purify quercetin flavonoid from other complex matrices. 相似文献
72.
Khalil Yamani Hugo Pierre Dr. Alexis Archambeau Dr. Christophe Meyer Prof. Dr. Janine Cossy 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(42):18663-18667
Catalytic enantioselective access to disubstituted functionalized gem-difluorocyclopropanes, which are emerging fluorinated motifs of interest in medicinal chemistry, was achieved through asymmetric transfer hydrogenation of gem-difluorocyclopropenyl esters, catalyzed by a Noyori–Ikariya (p-cymene)-ruthenium(II) complex, with (N-tosyl-1,2-diphenylethylenediamine) as the chiral ligand and isopropanol as the hydrogen donor. The resulting cis-gem-difluorocyclopropyl esters were obtained with moderate to high enantioselectivity (ee=66–99 %), and post-functionalization reactions enable access to valuable building blocks incorporating a cis- or trans-gem-difluorocyclopropyl motif. 相似文献
73.
Chen Zhao Dr. Gui-Liang Xu Dr. Tianshou Zhao Dr. Khalil Amine 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(40):17787-17793
Electrolyte modulation simultaneously suppresses polysulfide the shuttle effect and lithium dendrite formation of lithium–sulfur (Li-S) batteries. However, the sluggish S redox kinetics, especially under high S loading and lean electrolyte operation, has been ignored, which dramatically limits the cycle life and energy density of practical Li-S pouch cells. Herein, we demonstrate that a rational combination of selenium doping, core–shell hollow host structure, and fluorinated ether electrolytes enables ultrastable Li stripping/plating and essentially no polysulfide shuttle as well as fast redox kinetics. Thus, high areal capacity (>4 mAh cm−2) with excellent cycle stability and Coulombic efficiency were both demonstrated in Li metal anode and thick S cathode (4.5 mg cm−2) with a low electrolyte/sulfur ratio (10 μL mg−1). This research further demonstrates a durable Li-Se/S pouch cell with high specific capacity, validating the potential practical applications. 相似文献
74.
The mycotoxin zearalenone (ZEA) prompts reproductive toxicity due to its strong estrogenic effects. In this work, an electrochemical sensor for determination of ZEA was developed by electropolymerization of a molecularly imprinted poly (o‐phenylenediamine) (PPD) film on screen‐printed gold electrode (SPGE) surface. The sensor was examined by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) using K3[Fe(CN)6]/K4[Fe(CN)6] as redox probe. The molecularly imprinted polymer (MIP) sensor showed a wide determination range from 2.50 to 200.00 ngmL?1 for ZEA. The Limit of detection (LOD) was calculated to be 0.20 ngmL?1, based on the signal to noise (S/N) ratio equal to 3.0. The sensor displayed good repeatability, with RSD values≤4.6 %, and maintained 93.2 % of its initial response after storage for 10 days in air at room temperature. The developed method was successfully applied for the determination of ZEA in corn flakes with mean recoveries ranged from 96.2 % to 103.8 % and RSDs within the interval of 2.1 % to 3.8 %. 相似文献
75.
Mohammed Belmekki Mouffak Benchohra Khalil Ezzinbi 《Applied Mathematics Letters》2011,24(11):1810-1816
In this paper, we establish sufficient conditions for the existence of solutions for some partial functional differential equations with state-dependent delay; we assume that the linear part is not necessarily densely defined and satisfies the well-known Hille–Yosida conditions. Our approach is based on a nonlinear alternative of Leray–Schauder type and integrated semigroup theory. An application is provided to a reaction–diffusion equation with state-dependent delay. 相似文献
76.
The present paper investigates phenomena brought about into the classic peristaltic mechanism by inclusion of non-Newtonian effects through a porous space in a channel. The peristaltic motion of a second-order fluid through a porous medium was studied for the case of a planar channel with harmonically undulating extensible walls. The system of the governing nonlinear PDE is solved by using the perturbation method to second-order in dimensionless wavenumber. The analytic solution has been obtained in the form of a stream function from which the axial pressure gradient has been derived. The flow is investigated in a wave frame of reference moving with velocity of the wave. Numerical calculations are carried out for the pressure rise and frictional force. The features of the flow characteristics are analyzed by plotting graphs and discussed in detail. 相似文献
77.
Abd El-Moneim Anwar Mohamed Mohamed Abd El-Hady Kassem Mohamed Abd Allah El-Hadidy 《Applied Mathematical Modelling》2011,35(9):4127-4139
This paper investigates a search problem for a brownian target motion on one of n-intersected real lines in which any information of the target position is not available to the searchers all the time. We have n-searchers start searching for the target from the origin that is the intersection point of these lines. Each of the searchers moves continuously along his line in both directions of the starting point. The purpose of this paper is to formulate a search model and find the condition under which the expected value of the first meeting time between one of the searchers and the target is finite. Also, we show the existence of the optimal search plan which minimizes the expected value of the first meeting time and find it. 相似文献
78.
M.A. Abid H. Abu HassanZ. Hassan S.S. NgS.K. Mohd. Bakhori N.H. Abd. Raof 《Physica B: Condensed Matter》2011,406(8):1379-1384
Raman and Fourier transform infrared (FTIR) spectroscopies have been utilized to measure long-wavelength optical lattice vibrations of high-quality quaternary AlxInyGa1−x−yN thin films at room temperature. The AlxInyGa1−x−yN films were grown on c-plane (0 0 0 1) sapphire substrates with AlN as buffer layers using plasma assisted molecular beam epitaxy (PA-MBE) technique with aluminum (Al) mole fraction x ranging from 0.0 to 0.2 and constant indium (In) mole fraction y=0.1. Pseudo unit cell (PUC) model was applied to investigate the phonons frequency, mode number, static dielectric constant, and high frequency dielectric constant of the AlxInyGa1−x−yN mixed crystals. The theoretical results were compared with the experimental results obtained from the quaternary samples by using Raman and FTIR spectroscopies. The experimental results indicated that the AlxInyGa1−x−yN alloy had two-mode behavior, which includes A1(LO), E1(TO), and E2(H). Thus, these results are in agreement with the theoretical results of PUC model, which also revealed a two-mode behavior for the quaternary nitride. We also obtained new values of E1(TO) and E2(H) for the quaternary nitride samples that have not yet been reported in the literature. 相似文献
79.
Ahmed M. Donia Asem A. Atia Hassnaa M. Abd El-Latif 《Journal of Dispersion Science and Technology》2014,35(3):380-389
Cellulose was modified via chlorination using phosphorous oxychloride followed by functionalization with amine and thiol moieties. The obtained modified cellulose samples were investigated by means of FTIR, TGA, TEM, and nitrogen-adsorption surface area (BET). The BET measurements showed a remarkable increase in the surface area of Cell-N-S (477.7 m2/g) and Cell-N (706 m2/g). The resins gave an uptake capacities of 38 and 7.2mmol/g for Cell-N-S and Cell-N, respectively toward Hg(II) from its solutions. These values are considered much better compared with other reported resins. Regeneration of the resins was achieved effectively using acidified thiourea. 相似文献
80.
The N-arylation of indoles with a variety of aryl bromides is reported using copper oxide nanoparticles as a heterogeneous catalyst. These copper oxide nanoparticles, which were produced in a novel, facile, and scalable fashion via an electrospinning technique, resulted in an excellent product yield under mild conditions. Moreover, the catalyst was easily recovered and reused several times without significant loss of activity. 相似文献